An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes.
نویسندگان
چکیده
The dissociation of one pyridine of a pentadentate ligand (N4Py) from the Co centre was found to be responsible for the formation of a Co(III) hydride species, an indispensable intermediate for photocatalytic proton reduction.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 49 شماره
صفحات -
تاریخ انتشار 2014